2-­Methylbutane on reacting with bromine in the presence of sunlight gives mainly

2-­Methylbutane on reacting with bromine in the presence of sunlight gives mainly

  1. 2-­bromo­-2-­methylbutane
  2. 1-­bromo-­3-­methylbutane
  3. 2-­bromo-­3-­methylbutane
  4. 1-­bromo-­2-­methylbutane

Answer

The reactivity order of abstraction of H atoms towards bromination of alkane is 3°H (tertiary) > 2°H (secondary) > 1°H (primary).

Bromine will be substituted to the Hydrogen where carbon has least number of hydrogen atoms. In this case, methyl group is attached at second position, so only 1 hydrogen is attached to second carbon atom (tertiary).

The correct option is A.